Effect of Elevated Temperature on Concrete Strength

effect of fire on concrete

Effect of Elevated Temperature on Concrete Strength

Concrete structures could be exposed to high temperatures due to different reasons, mainly during exposure to fire; another one could be when the structure or its elements are a part of industrial installations.

At high temperatures, Portland cement concretes undergo important changes in their properties, due to formation of cracks between cement paste and aggregate and associated thermal incompatibility between the two ingredients, resulting in damages ranging from cracking and spalling of concrete surface (short duration exposure) to the structural element complete destruction as a result from the loss of its mechanical strength (long duration exposure).

An experiment is conducted with the following details:

A concrete mixture was prepared by using ordinary Portland cement, crushed limestone aggregate with maximum size of 15 mm, and water.  A plasticizer was also utilized in order to improve the workability of the mixture. One hundred and 150 mm cube concrete specimens were cast and cured in water for 28 days. Afterwards, they were air-dried in the laboratory for 7 days and oven-dried at 105◦C for another 7 days. Finally, the specimens were exposed to high temperatures ranging from 200 to 1200◦C for 2 h. The heating rate was 1◦C/min. After such a treatment, the specimens were allowed to cool with a rate of 1◦C/min. Then, the specimens were stored in dry condition at room temperature for 7 days until testing. The compressive strength of the specimens was determined. The test results obtained from unheated specimens are 69.2 MPA for 100 mm cube and 76.6 MPA for 150 mm cube. The microstructures of concrete specimens were also examined by scanning electron microscope (SEM) analyses after exposure.

Results of Experiment

Visual inspections

The assessment of fire-damaged concrete usually starts with visual observation of color change, cracking, and spalling of concrete surface. The surface textures of concrete specimens exposed to high temperatures are illustrated in Figure 1. There was no visible effect on the surface of the specimens heated up to 400C. The concrete started to crack when the temperature reached to 600C, but the effect was not significant at that temperature level. The cracks were pronounced at 800C and extensively increased at 1000C. The cracks highly enlarged and partly spalling of the sample was observed after exposure to 1200C. This can be attributed to continuous crack formation due to very high temperatures.

concrete specimens exposed to high temperatures
Figure 1. Surface textures of the concrete specimens exposed to high temperatures.

Moreover, the spalling may substantially reduce the load-bearing capacity of a fire-damaged concrete. Furthermore, the concrete can be broken into pieces often without advance notice due to thermal explosions. The retained properties of concrete after exposure to a fire can be primarily assessed by observing the color of the concrete. The inner surfaces of the concrete specimens are shown in Figure 2. The crushed limestone aggregates used in the production of concrete became dark pink, pink, off-white, and white when the exposure temperature increased to 400, 600, 800, and 1000C, respectively. It was observed that the aggregates completely decomposed and lost their integrity as the temperature reached to 1200◦C. However, further color image analyses are required in order to examine the changes in the color of the cement paste. According to Li et al. straw yellow, off-white, and red appear when the concrete is subjected to temperatures of 400, 800, and 1000C, respectively. Yuzer et al. studied compressive strength–color change relation in mortars at high temperatures. They observed that the hue of color changed a little from yellow into greenish yellow when the temperature rose from 20 to 600C, it was yellow at 600C and it became reddish yellow when the temperature increased from 600 to 1200C.

concrete exposed to fire
Figure 2. Inner surfaces of concrete specimens exposed to high temperatures

Compressive strength test results

The strength of concrete is a direct requisite of all concrete structures that resist applied loads. The researchers found that one of the main effects of high temperatures on concrete structures was the reduction in compressive strength of concrete. The retained compressive strength values of the concrete specimens after exposure to high temperatures are presented in Figure 3.

concrete exposed to fire
Figure 3. Retained compressive strength of the concrete specimens exposed to high temperatures.

The retained compressive strength was calculated as the percent compressive strength of concrete after exposure with respect to strength of unheated specimen. The test results revealed that the retained compressive strength significantly decreased with increase in exposure temperature. It slightly reduced upon heating at 400C and there was a sharp reduction beyond that point. For example, the retained compressive strength values were 82 and 10% when the concrete was heated at 400 and 800C, respectively. When the exposure temperature exceeded 1000C, the specimens started to decompose and lost their binding capacities. The retained compressive strengths of concrete specimens after exposure to 1000 and 1200C were measured as 1.9 and 0.9%, respectively.

The reductions in compressive strength of concrete when exposed to elevated temperatures can be attributed to the dehydration of concrete by driving out of free water, interlayer water, and chemically combined water. The loss of physically bound water significantly affects the mechanical properties of the concrete exposed to elevated temperatures. The shrinkage due to the evaporation of water and steam pressure results in cracking and spalling of concrete. The integrity and load-bearing capacity of the structure may be imperilled. Furthermore, the explosive thermal spalling of concrete during fire occurs mostly without advance notice. It should also be noted that the presence of loading during heating influences the strength of concrete since the failure mode is generally thermal spalling when concrete is exposed to high temperature. The magnitude of concrete creep at elevated temperatures is much bigger than at room temperature.

SEM micrographs

SEM micrographs of pre- and post-heated concrete specimens up to 1200C are illustrated in Figure 4. The micrographs taken from the core of the cubes revealed hydrated phases such as CSH gels (marked CSH) and calcium hydroxide [Ca(OH)2] (marked CH). SEM studies on concrete specimens exposed to 800C revealed significant changes in the microstructure of the concrete due to the microcracks, voids, partly deteriorated CSH gels, and deformed CH crystals. The increase in temperature to 800C resulted in several microcracks generally intermingled with voids.

concrete exposed to fire
Figure 4. SEM micrographs of concrete specimens: (a) at ambient temperature; (b) at 800◦C; and (c) at 1200◦C.

SEM micrograph of specimen subjected to 1200C showed that the microstructure of the concrete completely disrupted at that temperature level. The micrograph showed that the carbonation reaction was completely developed resulting in the decomposition of limestone aggregate into CaO and CO2. In addition to that, large amount of gaps were observed in the whole area of the examined sample. This can be attributed partly to pulverization of the limestone aggregate and partly to deterioration of the cement paste. Therefore, the very low retained compressive and splitting tensile strengths may be attributed to deterioration of the structure which may make the  concrete more susceptible to further destruction.

Li M., Qian C.X., Sun W., (2004) “Mechanical properties of high-strength concrete after fire”, Cement and Concrete Research

Yuzer N., Akoz F., Ozturk L.D., (2004), “Compressive strength—colour change relation in mortars at high temperature”, Cement and Concrete Research

2 comments

  1. very good research work.any how we use jackets with embedded ceraz wool.the enclosure may be of .2mm stainless steel sheet.this cover will control the concrete from atmospheric or plant released gases.i suggest cover shall be minimum 60 mm for columns,50mm for beams and minimum 30mm for slabs.although it does not conform to code of practice.But is important to protect rcc structures.

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